姓名: 曹 鑫
职称: 副教授
学位：博士
邮箱：xincao@njnu.edu.cn
地址：南京师范大学仙林校区化行楼302
教育工作经历
· 研究员 (2022.06-至今)
南京师范大学 化学与材料科学学院 江苏省新型动力电池重点实验室
· 博士后 (2021.09-2022.05)
日本国立产业技术综合研究所 (AIST) 能量转换研究部门
职务：特别研究员
· 博士 (2018.10-2021.09，国家留学基金委公派计划)
日本筑波大学 系统信息工程学院
· 硕士 (2015.09-2018.07)
陕西师范大学 材料科学与工程学院
· 本科 (2011.09-2015.07)
陕西科技大学 材料科学与工程学院
研究方向
· 高能量密度锂离子电池关键材料
· 新型钠离子电池电极开发与机理研究
· 电化学原位测试与表征
· 电化学储能器件设计
成果介绍
近五年以第一作者/通讯作者在Joule (Cell 子刊)，Adv. Mater.，Angew. Chem. Int. Ed.，Adv. Energy Mater.，Adv. Funct. Mater.，Energy Storage Mater.，ACS Energy Lett.，Sci. Bull.等国际顶级刊物上发表SCI论文20余篇。学术链接：https://orcid.org/0000-0002-2548-043X，部分论文如下：
1. X. Zhao (22硕士研究生，获国家奖学金，研究生一等奖学金), X. Cao* and H. Zhou*, Solid-state exfoliation growth mechanism of single-crystal Li-rich layered cathode materials. Energy Storage Materials, 2025, 104093.
2. X. Zhao (22级硕士研究生), Y. Wang*, C. Li*, X. Cao* and H. Zhou*, Tailoring oxygen redox activity and accelerating Li+ diffusion via Ti substitution within Li-O-vacancy configurations. Advanced Functional Materials, 2025, DOI: 10.1002/adfm.202504973.
3. X. Zhao (22级硕士研究生), X. Cao* and H. Zhou*, Structure design for high-performance Li-rich Mn-based layered oxides, O2- or O3-type cathodes, what’s next? Accounts of Materials Research, 2024, 5, 307-315.
4. W. Ma (21级硕士研究生), X. Cao* and Y. Zhou*, Ultra-Fast-Charging, Long-Duration, and Wide-Temperature-Range Sodium Storage Enabled by Multiwalled Carbon Nanotube-Hybridized Biphasic Polyanion-Type Phosphate Cathode Materials. ACS Applied Materials & Interfaces, 2024, 16(27), 34819-34829.
5. J. Ai (23级硕士研究生), X. Cao* and H. Zhou*, Impact of Lithium Sources on Growth Process and Structural Stability of Single-Crystalline Li-rich Layered Cathodes. Batteries & Supercaps, 2024, 8, e202400425.
6. X. Zhao (22级硕士研究生), X. Cao*,Y. Qiao* and H. Zhou*. Research progress in cathode materials of secondary batteries with high specific energy based on anionic charge compensation mechanism. Chinese Science Bulletin, 2025, 70, 1118-1131.
7. J. Zhu (21级本科生，保研至厦门大学化学化工学院), X. Cao* and P. Wu*, Cyanosol-enabled ultrafine alloy nanocrystals on graphene as a hybridization matrix for long-life and high-rate silicon anodes. New Journal of Chemistry, 2024，10.1039/d4nj01660b.
8. X. Zhao (22级硕士研究生), X. Cao*, P. Wu* and H. Zhou*, Perspective on High-Stability Single-Crystal Li-Rich Cathode Materials for Li-Ion Batteries. ACS Applied Materials & Interfaces, 2024, 16(19), 24147–24161.
9. G. Zhang (博士研究生), C. Chen, C. Xu, J. Li, H. Ye, A. Wang, X. Cao*, K. Sun, J. Jiang, Unraveling the Microcrystalline Carbon Evolution Mechanism of Biomass-Derived Hard Carbon for Sodium-Ion Batteries. Energy & Fuels, 2024, 38(9),8326-8336.
10. P. Dai (22级硕士研究生，获国家奖学金), W. Ma, Y. Zhou, Y. Tang, X. Cao*, P. Wu* and H. Zhou*, Superfast Phase Transformation Driven by Dual Chemical Equilibrium Enabling Enhanced Electrochemical Energy Storage. Advanced Functional Materials, 2024, 34, 202308357.
11. P. Dai (22级硕士研究生), X. Cao* and P. Wu*, Central metal coordination environment optimization enhances Na diffusion and structural stability in Prussian blue analogues. Energy Storage Materials, 2025, 74,103890.
12. Z. Zhan (21级硕士研究生), T. Huang, J. Zhu, X. Cao*, Y. Zhou, Y. Tang and P. Wu*, Interpenetrating gel-enabled uniform integration of metal and carbon dual matrices with nanoporous silicon for high-performance lithium storage. CrystEngComm, 2024, 26, 639-646.
13. J. Sun (博士研究生), X. Cao*, W. Yang, E. Yoo and H. Zhou*, Impact of particle size on the kinetics and structure stability of single-crystal Li-rich cathode materials. Journal of Materials Chemistry A, 2023, 11, 13956-13964.
14. J. Sun (博士研究生), X. Cao* and H. Zhou*, Advanced single-crystal layered Ni-rich cathode materials for next-generation high-energy-density and long-life Li-ion batteries. Physical Review Materials, 2022, 7, 070201.
15. J. Sun (博士研究生), X. Cao*, H. Yang, P. He, M. A. Dato, J. Cabana and H. Zhou*, The origin of high-voltage stability in single-crystal layered Ni-rich cathode materials. Angewandte Chemie International Edition, 2022, 134, 202207225.
16. J. Sun1 (博士研究生), C. Sheng1, X. Cao*, P. Wang, P. He*, H. Yang, Z. Chang, X. Yue and H. Zhou*, Restraining oxygen release and suppressing structure distortion in single-crystal Li-rich layered cathode materials. Advanced Functional Materials, 2022, 32, 2110295.
17. X. Cao1, H. Li1, Y. Qiao*, P. He, Y. Qian, X. Yue, M. Jia, J. Cabana and H. Zhou*, Reversible anionic redox chemistry in layered Li4/7[□1/7Mn6/7]O2 enabled by stable Li-O-vacancy configuration. Joule, 2022, 6, 1290-1303.
18. X. Cao, J. Sun, Z. Chang, P. Wang, X. Yue, J Okagaki, P. He and H. Zhou*, Enabling long-term cycling stability within layered Li-rich cathode materials by O2/O3-type biphasic design strategy. Advanced Functional Materials, 2022, 31, 202205199.
19. X. Cao, Y. Qiao*, M. Jia, P. He and H. Zhou*, Ion-exchange: a promising strategy to design Li-rich and Li-excess layered cathode materials for Li-ion batteries. Advanced Energy Materials, 2022, 12, 2003972.
20. X. Cao1, H. Li1, Y. Qiao*, Z. Chang, P. Wang, C. Li, P. He, X. Yue, J. Cabana and H. Zhou*, Triggering and Stabilizing Oxygen Redox Chemistry in Layered Li[Na1/3Ru2/3]O2 Enabled by Stable Li–O–Na Configuration. ACS Energy Letters, 2022, 7, 2349-2356.
21. X. Cao1, H. Li1, Y. Qiao*, M. Jia, X. Li, J. Cabana and H. Zhou*, Stabilizing anionic redox chemistry in a Mn-based layered oxide cathode constructed by Li-deficient pristine state. Advanced Materials, 2021, 33, 2004280.
22. X. Cao1, H. Li1, Y. Qiao*, M. Jia, H. Kitaura, J. Zhang, P. He, J. Cabana and H. Zhou*, Structure design enables stable anionic and cationic redox chemistry in a T2-type Li-excess layered oxide cathode. Science Bulletin, 2021, 67, 381-388.
23. X. Cao1, H. Li1, Y. Qiao*, M. Jia, P. He, J. Cabana and H. Zhou*, Achieving stable anionic redox chemistry in Li-excess O2-type layered oxide cathode via chemical ion-exchange strategy. Energy Storage Materials, 2021, 38, 1-8.
24. X. Cao and H. Zhou*, An indicator of designing layered sodium-ion oxide materials. Science Bulletin, 2021, 66, 753-754.
25. X. Cao1, H. Li1, Y. Qiao*, X. Li, M. Jia, J. Cabana and H. Zhou*, Stabilizing reversible oxygen redox chemistry in layered oxides for sodium-ion batteries. Advanced Energy Materials, 2020, 10, 1903785.
26. X. Cao1, X. Li1, Y. Qiao*, M. Jia, F. Qiu, Y. He, P. He and H. Zhou*, Restraining oxygen loss and suppressing structural distortion in a newly Ti-substituted layered oxide P2-Na0.66Li0.22Ti0.15Mn0.63O2. ACS Energy Letters, 2019, 4, 2409-2417.
27. X. Cao, J. He, H. Li, L. Kang, X. He, J. Sun, R. Jiang, H. Xu, Z. Lei and Z.-H. Liu*, CoNi2S4 nanoparticle/carbon nanotube sponge cathode with ultrahigh capacitance for highly compressible asymmetric supercapacitor. Small, 2018, 14, 1800998.
28. X. Cao, H. Li, J. He, L. Kang, R. Jiang, F. Shi, H. Xu, Z. Lei and Z.-H. Liu*, Preparation and formation process of α-MnS@MoS2 microcubes with hierarchical core/shell structure. Journal of Colloid and Interface Science, 2017, 507, 18−26.
基金主持参与情况
· 1. 国家自然科学基金面上项目(2018-2021)
· 2. 江苏省高等学校自然科学研究基金面上项目 (2023-2025)
· 3. 江苏省基础研究计划自然科学基金青年项目 (2023-2026)
· 4. 江苏省科协青年科技人才托举项目 (2023-2025)
· 5. 国家自然科学基金青年项目(2024-2026)
· 6. 南京市留学人员科技创新项目(2024-2025)
其他情况
· 硕博毕业生去向：南京林业大学博士后；南京大学化学化工学院攻读博士学位；南京大学现代工学院攻读博士学位；星恒电源电芯研发工程师；远景能源材料研发工程师；江苏正力新能研发工程师等。
· 本硕竞赛获奖：大学生创新创业项目；全国大学生节能减排社会实践与科技竞赛；中国青年碳中和创新创业大赛；江苏省科协创新创业大赛；LG新能源中国大学生动力电池创新竞赛等。
· 课题组每年招收本科生3-5名、硕士生2-3名、博士生1名，欢迎咨询联系或推荐合适人选，请将简历直接发送至xincao@njnu.edu.cn，期待你的加入！
