林军教授课题组和周小四教授课题组合作在JOURNAL OF ALLOYS AND COMPOUNDS发表研究论文

时间:2020-03-23 来源:化科院 点击数:

Uniform yolk-shell Fe7S8@C nanoboxes as a general host material for the efficient storage of alkali metal ions

Weng, WS (Weng, Wangsuo)[ 1 ] ; Xu, JY (Xu, Jingyi)[ 1 ] ; Lai, CL (Lai, Chenling)[ 1 ] ; Xu, ZH (Xu, Zhenhua)[ 1 ] ; Du, YC (Du, Yichen)[ 1 ] ; Lin, J (Lin, Jun)[ 1 ]*(林军); Zhou, XS (Zhou, Xiaosi)[ 1 ]*(周小四)


[ 1 ] Nanjing Normal Univ, Jiangsu Key Lab New Power Batteries, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Nanjing 210023, Peoples R China


JOURNAL OF ALLOYS AND COMPOUNDS,202003,817


Iron sulfides are potential anode materials for the reversible electrochemical storage of alkali metal ions (Li+, Na+, or K+) from the perspective of high theoretical capacity and relatively low cost. Nevertheless, their real application is greatly hampered by the inferior conductivity and the huge volume variations in the reaction with alkali metal ions. Few studies have examined desirable candidates that can be used as current host materials for alkali metal ions. In this work, a mild etching approach coupled with further sulfidation has been proposed for the precise design and preparation of uniform yolk-shell Fe7S8@C nanoboxes. The as-prepared yolk-shell Fe7S8@C nanoboxes exhibit excellent storage performance for alkali metal ions in the aspects of high specific capacity, superior cyclic stability, and good rate performance. The excellent electrochemical behaviour is attributed to the rational design of yolk-shell nanostructure.

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https://www.sciencedirect.com/science/article/abs/pii/S0925838819339787?via%3Dihub


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